Water Quality Testing in Thermal Power Plants: A Complete Guide to Key Parameters per National Standards & Online Instruments

2025.10.31
ERUN

Introduction: Why is Water Quality the "Lifeline" of a Thermal Power Plant?

In simple terms, the key parameters for water quality testing in thermal power plants include pH, conductivity, dissolved oxygen, silica, sodium ions, phosphate, and more. These are primarily monitored in real-time, continuously, using online chemical analyzers.

This is no overreaction. Imagine the plant boiler as a giant "pressure cooker." Poor water quality instantly triggers three major crises: scaling, corrosion, and carryover. Just a 1mm layer of scale can increase fuel consumption by 2% to 5%. More alarmingly, corrosion can lead to tube bursts and forced outages, with unplanned shutdowns often causing millions in economic losses. Therefore, real-time online water quality monitoring is no longer an "auxiliary" task but the "nerve center" ensuring safe, economical, and environmentally compliant plant operation.

Module 1: Feedwater System Monitoring – Guarding the "First Line of Defense"

Feedwater, the treated water supplied to the boiler, must be of high purity as it directly determines the internal environment of the boiler. The national standard GB/T 12145-2022 "Water and Steam Quality for Thermal Power Generation Units and Steam Power Equipment" specifies clear requirements.

  • Key Parameters & Instruments:

    • pH Value: The standard typically requires a range of 8.8~9.3 (for systems with copper alloys) or 9.2~9.6 (all-ferrous systems). Low pH accelerates acid corrosion, while high pH can cause caustic corrosion. Online pH analyzers are essential, with electrodes resistant to high temperature and pressure.

    • Dissolved Oxygen: Must be reduced to below 7 μg/L, even below 5 μg/L for supercritical units. Dissolved oxygen is a primary cause of oxygen corrosion in the boiler system. Online dissolved oxygen analyzers (using polarographic or luminescent methods) monitor deaerator performance in real-time, providing precise data for oxygen scavenger dosing.

    • Conductivity: The cation conductivity (after cation exchange) of feedwater is a comprehensive indicator of the total ionic impurities. Online conductivity sensors are simple in structure but provide critical data, quickly indicating whether the polishing plant system is failing.

Application Scenario: At a 600 MW subcritical unit, operators noticed a slow rise in dissolved oxygen from 3 μg/L to 8 μg/L via the online dissolved oxygen analyzer. This prompted an inspection that found loose internal parts in the deaerator, averting a system-wide oxygen corrosion risk.

Module 2: Boiler Water & Steam System – The "Quality Gatekeepers" for High-Purity Steam

The water inside the boiler drum and the generated steam operate under high temperature and pressure, demanding even stricter quality control.

  • Key Parameters & Instruments:

    • Silica (SiO₂): Silica becomes highly soluble in high-pressure steam and can deposit on turbine blades, forming hard, tenacious silicate scales that severely impact output and efficiency. The national standard sets strict limits for SiO₂ in steam (e.g., ≤20 μg/kg). Online silica analyzers use the molybdenum blue colorimetric method to achieve precise monitoring at μg/L levels.

    • Sodium Ions: Sodium is a representative of salts, and its content is a key marker for steam purity. Online sodium ion monitors (using ion-selective electrodes) are extremely sensitive, detecting sodium at parts-per-trillion (ppt) levels, acting as a "stethoscope" for diagnosing superheater or reheater tube leaks.

    • Phosphate: For boiler water treated with phosphate, maintaining a specific PO₄³⁻ concentration (typically 2~10 mg/L) helps form a protective film on metal surfaces and regulates pH. Online phosphate analyzers also use colorimetric methods for automated chemical feed control.

Instrument Reference: In recent tender documents for power plant chemical analyzers, integrated solutions like the ERUN-SZ Series Power Plant Online Boiler Water Analyzer frequently appear. It integrates measurement modules for various parameters (e.g., silica, phosphate, hydrazine) into a single unit, reducing sample tubing, improving data centralization, and enhancing maintenance efficiency, making it particularly suitable for deployment in space-limited areas.

Module 3: Condensate System – The "Quality Control Center" for Reuse

The steam that condenses after performing work in the turbine is the plant's primary water recycle. However, this condensate is highly susceptible to contamination from cooling system leaks.

  • Key Parameters & Instruments:

    • Conductivity & Sodium Ions: These remain the most sensitive indicators for detecting cooling water (e.g., seawater) leaks. A step-change increase in the online sodium analyzer's reading almost immediately confirms a condenser tube leak.

    • Dissolved Oxygen: Monitors the tightness of the condensate system for any air in-leakage.

Case Study: A coastal 1000 MW unit experienced a sudden deterioration in condensate quality, which was difficult to locate through routine inspection. It was the real-time data trends from the online conductivity and sodium analyzers installed at the condensate polisher outlet that pinpointed the leak to a specific location in the B-side condenser, enabling rapid isolation and repair.

Conclusion: The Value of Building an Intelligent Water-Steam Monitoring System

In summary, modern water quality management in thermal power plants has evolved beyond manual sampling towards automation and intelligence centered on online chemical analyzers. This system is not just about compliance with national standards; it is a crucial strategy for power plants to achieve:

  • Safe Operation: Early warning of corrosion and scaling risks, preventing major failures.

  • Economic Benefits: Improved heat rate, extended equipment life, and reduced outage losses.

  • Environmental Compliance: Optimized blowdown and chemical dosing, reducing chemical consumption and environmental impact.

Investing in a reliable and accurate online water analysis system is like employing a tireless "chemical doctor" for the power plant, whose long-term return far outweighs the initial investment. When selecting equipment, focus on measurement accuracy, long-term stability, anti-interference capability, and ease of integration with the plant's DCS/SIS systems.

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